GC
IndustriesEnergy & Chemicals
ManufacturerThermo Fisher Scientific
Importance of the topic
Monitoring and analysis of dissolved gases in transformer oil is critical for early detection of electrical faults in power transformers. This technique helps link gas generation profiles to specific fault types and severity levels, supporting predictive maintenance and reducing downtime.
Objectives and study overview
This application note outlines the performance of a custom configured Transformer Oil Gas Analyser (TOGA) designed to meet and exceed ASTM D3612c requirements. Key aims include demonstrating automated headspace sampling, sensitive multi-component detection, and integration with common chromatography data systems.
Methodology and instrumentation
The analyser employs closed-loop headspace sampling coupled to a single-channel GC platform.
- Gas chromatograph: Thermo Trace 1300 GC or CompactGC
- Detectors: micro-TCD for permanent gases, FID with methaniser for CO and CO2
- Autosamplers: Teledyne Tekmar Versa (20×22 ml vials) or Thermo Triplus 300 (up to 120 vials of 10–22 ml)
- Carrier gas: Argon
- Sampling principle: automated closed-loop headspace equilibration at 70 °C
- Data systems: Chromeleon, ChromCard, OpenLab, EZChrom Elite/ChromQuest
- Optional: additional gas sampling valve for direct gas injection
Main results and discussion
Analysis of standard oil samples shows detection limits substantially better than ASTM D3612c specifications:
- CO2: 0.4 ppm (ASTM 25 ppm)
- Acetylene: 0.2 ppm (ASTM 1 ppm)
- Ethylene: 0.4 ppm (ASTM 1 ppm)
- Ethane: 0.6 ppm (ASTM 1 ppm)
- Hydrogen: 2 ppm (ASTM 5 ppm)
- Oxygen and Nitrogen: < 25 ppm (ASTM 50 ppm)
- Methane: 0.2 ppm (ASTM 1 ppm)
- Carbon monoxide: 0.3 ppm (ASTM 25 ppm)
Benefits and practical applications
The TOGA system offers:
- Automated high-throughput analysis of up to 120 samples
- Enhanced sensitivity and dynamic range (4 decades TCD, 7 decades FID)
- Compact design suitable for onsite laboratory installations
- Compliance and superior performance relative to ASTM standards
- Seamless integration with leading chromatography software
Future trends and potential applications
Advancements may include expanded analysis of heavier hydrocarbon fragments (C3, C4), integration with remote monitoring platforms, and enhanced data analytics for predictive diagnostics. Further miniaturization and enhanced detector technologies could enable onsite or real-time transformer health monitoring.
Conclusion
The TOGA analyser represents a robust, flexible, and high-performance solution for dissolved gas analysis in transformer oil. Its superior sensitivity, automation, and compact design make it well suited for preventive maintenance programs in the power industry.
Reference
ASTM D3612 Part C: Standard Test Method for Analysis of Gases in Electrical Insulating Oil by Gas Chromatography
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